Unravelling the effect of crystal lattice compression on the supercapacitive performance of hydrothermally grown nanostructured hollandite α-MnO2 induced by incremental growth time

Abstract

Manganese oxide (α-MnO₂) nanoparticles are highly recognised for their use in supercapacitor applications. This study demonstrates the successful synthesis of flower-like and nanorods hollandite α-MnO₂ by a simple one-pot hydrothermal technique at various reaction times. The synthesised nanoparticles were characterised by various physicochemical and electrochemical characterisation techniques. The influence of the various reaction times on the structural and morphological properties was evaluated by X-ray diffraction (XRD) and scanning electron microscope. XRD patterns revealed that the synthesized MnO₂ nanoparticles are tetragonal structures with crystallite sizes ranging from 13.69 to 20.37 nm estimated from the Williamson-Hall method. Moreover, the functional groups and surface area were examined by Fourier transform infrared spectroscopy and Bruner-Emmert-Teller, respectively. Furthermore, the compositional elements were studied by X-ray photoemission spectroscopy and energy-dispersive X-ray spectroscopy. Finally, the electrochemical performances were studied using cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy (EIS). The GCD characteristics revealed that the optimised α-MnO₂ has a good capacitive behaviour, which predicts the potential application in energy storage. Electrochemical studies revealed that the 3 h-MnO₂ sample exhibited a superior electrochemical behaviour and demonstrated a high specific capacitance of 132 F/g at a current density of 1A/g.