Transforming wastewater treatment: Recent advancements in Catalytic Wet Air Oxidation with pillared clay catalysts for phenol remediation

Abstract

Catalytic Wet Air Oxidation (CWAO) has recently been recognized as a promising technique for degrading persistent organic pollutants, such as phenol, in wastewater. Among various catalysts, Pillared Interlayer Clays (PILCs) stand out due to their high specific surface area and porous nature. This review delves into the latest progress in CWAO processes utilizing PILCs for the degradation of organic contaminants such as phenol in wastewater. It meticulously assesses the synthesis of PILCs, and their structural properties, including monolithic forms, to understand their effect on catalyst efficiency. Key insights into how these attributes affect the phenol degradation rate and the CWAO process's stability are discussed, providing crucial direction for enhancing catalyst performance. The review highlights the significance of choosing catalysts that offer a balance between cost-efficiency and operational efficacy under mild conditions. The recent results are reported, summarized, and compared, thus proving the feasibility of using PILCs as promising materials for phenol removal. The reaction parameters, phenol conversion, and degradation mechanisms are highlighted. The catalytic efficiency of PILCs was significantly affected by the synthesis methods and reaction parameters, and outperformed most costly catalysts. PILCs are highlighted as especially advantageous catalysts, offering strong performance at lower costs, which boosts the up-scaling opportunities of CWAO methods. This analysis also points out research gaps and proposes directions for future studies, such as exploring innovative PILC synthesis methods to improve their catalytic effectiveness and durability further. It stresses the need to incorporate environmental and sustainability considerations into catalyst design and selection, aligning with the principles of green chemistry in wastewater treatment. Finally, we conclude that proposing new directions for PILCs in CWAO in further naturally-based surface modifications, is also a promising approach for PILCs to perform more efficiently.