MARATTO

article · Scientific African

The use of coconut shell ash as partial replacement of cement to improve the thermal properties of concrete and waste management sustainability in Nigeria and Africa, for radiation shielding application

202521 citationsOpen accessAbubakar Tafawa Balewa University

In plain language

This study evaluated concrete formulations that replace part of traditional cement with coconut shell ash for radiation shielding purposes. Coconut shells were processed into fine ash and blended into concrete mixes either alone or modified with barite and lime across seven test formulations. The concrete samples demonstrated densities between 2.2 and 2.40 grams per cubic centimetre. While ordinary coconut shell ash slightly reduced the linear attenuation coefficient against gamma rays at 0.081 MeV, the barite-lime-modified formulations increased this attenuation by up to 14.65 percent. In addition, the barite-lime-modified mixes showed good thermal stability at high temperatures and enhanced mechanical strength. The highest replacement levels provided the greatest waste management benefit alongside 90 percent cost effectiveness, with the 15 percent barite-lime-modified blend identified as the optimal combination for shielding materials.

Key takeaways

  • Coconut shell ash was processed with a 10 percent yield by weight and incorporated into concrete as a partial cement substitute.
  • Formulations containing barite-lime-modified coconut shell ash improved gamma-ray attenuation by up to 14.65 percent at 0.081 MeV compared to standard concrete.
  • Unmodified coconut shell ash reduced gamma-ray linear attenuation coefficients by up to 5.28 percent.
  • The barite-lime-modified ash enhanced concrete mechanical strength and high-temperature thermal stability.
  • A 15 percent replacement using barite-lime-modified ash proved optimal, offering 90 percent cost effectiveness and the highest waste management benefits.

Why it matters

Traditional concrete production consumes significant resources, while agricultural residues like coconut shells often end up as unmanaged waste. Integrating treated agricultural waste into specialized concrete offers a way to lower production costs and support waste management. Crucially, enhancing concrete to better absorb gamma radiation creates opportunities for safer, more sustainable protective shielding in environments where radiation and high temperatures are present.

Commercialisation angle

This research provides applied laboratory testing for construction material manufacturers developing specialized radiation-shielding concrete. The technology could be relevant to facilities requiring structural radiation protection, such as medical radiotherapy centres or nuclear installations seeking cost-effective, high-temperature-stable shielding. Currently at an early-stage experimental formulation phase, further standardisation and field testing would be necessary before industrial adoption.

AI-generated from the published abstract. Always read the original work before citing.

Abstract

This research partially replaced cement with coconut shell ash (CSA) to produce seven concrete samples, assessing the influence on the thermal, structural and mechanical characteristics of the resulting concrete for radiation shielding application. 3.8 kg of coconut shell was washed, dried and burnt (in muffle furnace at 200 °C) into ashes of total weight 0.38 kg at 10% yield/weight. The resulting ash was pulverized and sieved to fine powder. The control concrete (cement, sand and granite) was mixed with varying percentages of ordinary-CSA and barite-lime-modified-CSA to form seven samples. The sample's densities which ranged between 2.2 g/cm 3 to 2.40 g/cm 3 were obtained by Archimedes’ method. The XRD results revealed the presence of albite, muscovite, quartz and orthoclase feldspar across our samples. A good thermal stability against high temperatures, as well as improved mechanical strength were noticed with increased barite-lime-modified-CSA. Compared to the control concrete CSA-0.00, the LAC of CSA-0.05, CSA-0.10, and CSA-0.15 decreases by 4.43%, 5.28%, and 3.03% at γ-ray energies of 0.081 MeV, while that of CSA-CH-B-0.05, CSA-CH-B-0.10, and CSA-CH-B-0.15 respectively increased by 8.77%, 10.20%, and 14.65% at the same γ-ray energies. Sample CSA-0.15 and CSA-CH-B-0.15 showed greatest waste-management (WM%) with 90% cost-effectiveness. Therefore, the introduction of barite-lime-modified-CSA to concrete matrix increases the mechanical, thermal and γ-ray shielding properties of the concrete materials, with CSA-CH-B-0.15 as optimum combination for concrete in shielding application, indicating that barite-modernized-CSA additive have positive impact on the γ-ray shielding performance of concrete compared to ordinary CSA additive.

Research topics

  • Radiation Shielding Materials Analysis
  • Innovative concrete reinforcement materials
  • Graphite, nuclear technology, radiation studies

Sustainable Development Goals

Read the original research

This page summarises published work. The authoritative version sits with the publisher.

DOI: 10.1016/j.sciaf.2025.e02578

Is something wrong with this record? Report it or request removal.

Discussion

Discuss this research

Have you built on this work, tried to replicate it, or seen it applied in practice? Share what you know. Verified researchers and MARATTO™ domain experts can open a discussion, and any member can reply. Contributions are reviewed before they appear.

No discussion yet. Open the first thread.