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article · New Journal of Chemistry

Synthesis and spectroscopic characterization of ternary copper(<scp>ii</scp>) complexes containing nitrogen and oxygen donors as functional mimics of catechol oxidase and phenoxazinone synthase

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Abstract

Two ternary copper(<sc>ii</sc>) complexes<bold>1</bold>[(Cu<sub>2</sub>Me<sub>4</sub>en)<sub>4</sub>(EDTA)] and<bold>2</bold>[(CuMe<sub>4</sub>en)<sub>2</sub>(MIDA)] containing the mixed ligand system of 1,1′,4,4′-tetramethylethylenediamine (Me<sub>4</sub>en) (L) and<italic>N</italic>-methyliminodiacetic (MIDAH<sub>2</sub>) (L′) or ethylenediaminetetraacetic acid (EDTAH<sub>4</sub>) (L′) were synthesized.

Research topics

  • Metal complexes synthesis and properties
  • Magnetism in coordination complexes
  • Metal-Catalyzed Oxygenation Mechanisms

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DOI: 10.1039/c9nj06131b

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