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Sustainable green synthesis and characterization of nanocomposites for synergistic photocatalytic degradation of Reactive Orange 16 in textile wastewater using CuO@A-TiO2/Ro-TiO2

202428 citationsOpen accessMenoufia University

Abstract

This paper explores the photocatalytic degradation of Reactive Orange 16 (RO16) dye in textile wastewater employing a novel CuO@A-TiO<sub>2</sub>/Ro-TiO<sub>2</sub> nanocomposite. The nanocomposite was synthesized via a hydrothermal technique, resulting in a monoclinic phase of leaf-shaped CuO loaded on a hexagonal wurtzite structure of rod-shaped ZnO, as confirmed by FE-SEM and XRD analyses. Optical experiments revealed band gap energies of 1.99 eV for CuO, 2.19 eV for ZnO, and 3.34 eV for the CuO@A-TiO<sub>2</sub>/Ro-TiO<sub>2</sub> nanocomposite. Photocatalytic degradation experiments showcased complete elimination of a 100 mg/L RO16 solution (150 mL) after 120 min of UV light illumination and 100 min of sunlight illumination, emphasizing the nanocomposite's efficiency under both light sources. The study further delves into the application of the CuO@A-TiO<sub>2</sub>/Ro-TiO<sub>2</sub> nanocomposite for the degradation of actual textile wastewater samples under sunlight irradiation. The results underscore the nanocomposite's remarkable efficacy in treating RO16 in textile wastewater, positioning it as a promising candidate for sustainable and efficient wastewater treatment applications. This research contributes valuable insights into the development of advanced photocatalytic materials for textile dye degradation in wastewater treatment.

Research topics

  • Advanced Photocatalysis Techniques
  • Advanced Nanomaterials in Catalysis
  • TiO2 Photocatalysis and Solar Cells

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DOI: 10.1038/s41598-024-63294-3

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