article · IUCrData
In the crystal of the title compound, [MnNi(CN) 4 (C 3 H 7 NO) 2 ] n , both metal cations lie on sites of 2/ m symmetry, with the Ni II ion being four-coordinate square-planar and the Mn II ion being six-coordinate octahedral. Both coordination spheres are slightly distorted from the ideal shapes. The {C[triple-bond]N→Mn} unit is distinctly non-linear and all four cyanido ligands on each [Ni(CN) 4 ] 2− unit coordinate to Mn II ions, leading to the formation of an infinite layer structure. Bond lengths and interbond angles are comparable to those in similar dimetallic, cyanido-bridged compounds.
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DOI: 10.1107/s241431462500762x
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