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Octakis(dibutylammonium) decamolybdate(VI)

2024Open accessUniversité de Thiès

Abstract

In the title salt, (C<sub>8</sub>H<sub>20</sub>N)<sub>8</sub>[Mo<sub>10</sub>O<sub>34</sub>], the [Mo<sub>10</sub>O<sub>34</sub>]<sup>8-</sup> polyanion is located about an inversion centre and can be considered as a <i>β</i>-type octa-molybdate anion to which two additional MoO<sub>4</sub> tetra-hedra are linked <i>via</i> common corners. The [Mo<sub>10</sub>O<sub>34</sub>]<sup>8-</sup> polyanions are packed in rows extending parallel to [001] and are connected to the di-butyl-ammonium counter-cations through N-H⋯O hydrogen-bonding inter-actions.

Research topics

  • Polyoxometalates: Synthesis and Applications
  • Metal-Organic Frameworks: Synthesis and Applications
  • Chemical Synthesis and Characterization

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DOI: 10.1107/s2414314624004632

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