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<i>catena</i> -Poly[[[pentaaquadysprosium(III)]-μ-5-azaniumylisophthalato] dichloride monohydrate]

Abstract

In the title compound, {[Dy(C<sub>8</sub>H<sub>6</sub>NO<sub>4</sub>)(H<sub>2</sub>O)<sub>5</sub>]Cl<sub>2</sub>·H<sub>2</sub>O} <sub><i>n</i></sub> the central Dy<sup>III</sup> atom is nine-coordinated by four oxygen atoms from two symmetry-related chelating carboxyl-ate groups and five water mol-ecules, resulting in a distorted polyhedral geometry best described as 'muffin'-type by continuous shape measure analysis. The bridging ligands generate infinite [10] chains and the structure is consol-idated by an extensive hydrogen-bonding network and weak π-π stacking inter-actions.

Research topics

  • Lanthanide and Transition Metal Complexes
  • Magnetism in coordination complexes
  • Crystal structures of chemical compounds

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DOI: 10.1107/s241431462501020x

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