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article · RSC Advances

Deciphering the influence of Pd <sup>II</sup> and Pd <sup>IV</sup> oxidation states on non-standard chemical bonds within bis(jN-heterocyclic carbene) complexes: insights from DFT

20246 citationsOpen accessUniversity of Douala

Abstract

) shows an increase in values from an abnormal to normal chelating mode in tetrahalides, whereas the opposite is observed for dihalide complexes. The lower π-backbonding ability of the metal, which is influenced by the quantity and size of halide ions involved, could be one possible explanation for this deficiency.

Research topics

  • N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
  • Organometallic Complex Synthesis and Catalysis
  • Coordination Chemistry and Organometallics

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DOI: 10.1039/d4ra03893b

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