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Chemical synthesis of Nd <sub> <i>x</i> </sub> Co <sub> 1− <i>x</i> </sub> Fe <sub>2</sub> O <sub>4</sub> hybrid nanoparticles for permanent magnet applications: structural, magnetic and electrical properties

202510 citationsOpen accessCairo University

Abstract

Nd-doped CoFe<sub>2</sub>O<sub>4</sub> spinel ferrites were synthesized <i>via</i> the sol-gel method, confirming a cubic spinel structure. Increasing Nd concentration expanded the lattice parameter (8.3900-8.4231 Å) and unit cell volume while reducing grain size. FT-IR analysis validated the spinel phase. Nd doping enhanced the dielectric constant by affecting space charge polarization and charge hopping, with conductivity following a Debye-type relaxation mechanism. Cole-Cole plots indicated grain boundary effects and polaron hopping conduction. Magnetic properties improved with Nd<sup>3+</sup> content, with <i>M</i> <sub>s</sub> and <i>H</i> <sub>c</sub> reaching 5.621 emu g<sup>-1</sup> and 143.43 Oe at 4% doping. A transition from an antiferromagnetic to a ferromagnetic state was observed, with a high Curie temperature (<i>T</i> <sub>m</sub>) of 292 °C, confirming a stable ferromagnetic phase. These findings highlight Nd-doped CoFe<sub>2</sub>O<sub>4</sub> as a promising candidate for permanent magnet applications.

Research topics

  • Magnetic Properties and Synthesis of Ferrites
  • Magnetic Properties of Alloys
  • Magnetic properties of thin films

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DOI: 10.1039/d5na00197h

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