Assessment of Hydrocarbon Contamination Using 2D Resistivity Imagining Method and Geochemical Analysis in Ibadan, Southwestern Nigeria

Abstract

The study examined the use of 2D resistivity imaging survey and geochemical analysis to map and assess the level of soil contamination due to hydrocarbon spillage in Araromi Auto Spare Parts Market Ibadan, Southwestern Nigeria. The objectives are to provide 2D inverted resistivity sections beneath the study area, delineate anomalously low resistivity zones indicative of long-term hydrocarbon contamination in the sections, and determine concentrations of Polycyclic Aromatic Hydrocarbons (PAHs) in the suspected soils. Five traverses were run using Wenner array with electrode spacing varied from 5 m to 15 m and station increment of 5 m. The resistivity data were processed by using 2D inversion procedure to generate the 2D inverted resistivity sections. Geochemical analysis was conducted on five soil samples collected at 1 m depth in the low resistivity zones delineated on the 2D inversion sections, to determine the concentration of Polycyclic Aromatic Hydrocarbons (PAHs) to assess the level of contamination. The 2D inverted sections delineated low resistivity anomalies, ranging from 1.25 Ωm to 5.54 Ωm, characteristic of mature biodegraded hydrocarbon contamination. The results of geochemical analysis revealed total PAH concentration of 1390 µg/kg to 16140 µg/kg suggesting that the study area is heavily contaminated by the used motor oil. The combined use of 2D resistivity imaging and geochemical analysis has shown that soils beneath the study area has been heavily contaminated by the used motor oil, and may constitute potential health risk to the soil and groundwater systems in its vicinity. The results are expected to serve as useful guide in planning remediation programme.