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1-[( <i>E</i> )-1-(2-Carboxy-6-methylphenyl)diazen-1-ium-2-yl]naphthalen-2-olate

Abstract

The title compound, C 18 H 14 N 2 O 3 , crystallizes with two zwitterionic molecules ( A and B ) in the asymmetric unit, each featuring an intramolecular N—H...O hydrogen bond. In the extended structure, A + A and B + B carboxylic-acid inversion dimers linked by pairwise O—H...O hydrogen bonds arise, which generate R 2 2 (8) loops in each case. The dimers are linked by weak C—H...π and π–π stacking interactions.

Research topics

  • Synthesis and Properties of Aromatic Compounds
  • Crystallography and molecular interactions
  • Crystal structures of chemical compounds

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DOI: 10.1107/s2414314625011484

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